Gravimetric Analysis of Metal Carbonate
Essay by ogmathmaster • December 1, 2016 • Lab Report • 1,034 Words (5 Pages) • 1,611 Views
Gravimetric Analysis of Metal Carbonate
Tamer El-Maghrabi, Lauren
October 3, 2016
Data:
Mass beaker: 136.192 g
Mass beaker + alkali metal carbonate: 137.716 g
Mass alkali metal carbonate: 1.524 g
Mass of two filter papers: .577 g
Mass beaker, filter papers, SrCO3: 138.262 g
Mass SrCO3: 1.493 g
Color of flame: Yellow
Calculations:
- Calculate the experimental percent of carbonate in the alkali metal carbonate.
1.493g SrCO3 X (1 mol SrCO3 / 147.6g SrCO3) X (1 mol CO3 / 1 mol SrCO3) X 59.98g CO3 / 1 mol CO3
= .6067g CO3
.6067g / 1.493g X 100 = 40.6 %
- Calculate the theoretical percent of carbonate in each alkali metal carbonate.
Li2CO3: 6.94 X 2 = 13.88
13.88 + 59.98 = 73.86
59.981 / 73.86 X 100 = 81.21%
Na2CO3: 22.99 X 2 = 45.98
45.98 + 59.98 = 105.96
59.98 / 105.96 X 100 = 56.61 %
K2CO3: 39.10 X 2 = 78.20
78.20 + 59.98 = 138.18
59.98 / 138.18 = 43.41 %
Rb2CO3: 85.47 X 2 = 170.94
170.94 + 59.98 = 230.92
59.98 / 230.92 X100 = 25.97%
1 a)
Show, by calculation, that the addition of 60 mL of .20 M SrCl2 is in excess and that the unknown alkali metal carbonate is the limiting reagent.
SrCl2:
Moles = concentration X Volume
60 mL / 1000 mL = .060 L
Moles = (.20 mol/L) X (.060L)
Moles = .012 mol
Co3 (aq): 1.524g mass of metal carbonate - .9037 g mass of sodium in the metal carbonate = .6203g CO3
.6203g CO3 X (1 mol CO3 / 59.98g CO3) = .01035 mol CO3
.012 moles Sr X (1 mol CO33 / 1 mol Sr ) = .012 mol CO3
.01035 mol CO3 X ( 1 mol Sr / 1 mol CO3 ) = .01035 mol Sr
It is assumed that strontium carbonate is insoluble. However, a very small amount of strontium carbonate is soluble in water
- What is the solubility of strontium carbonate?
Solubility product of SrCO3, Ksp = 5.60e-10
Solubility product Ksp = [Sr+2][Co3-2]
5.60e-10 = s2
s = 2.37e-5 mol/L
Discussion:
- Calculate the experimental percent of carbonate in the alkali metal carbonate.
By using the experimental mass for 1.493g SrCO3, I used stoichiometry to find the grams of carbonate. I then divided this mass by the original experimental mass and multiplied by 100 to get 40.6 %.
- Calculate the theoretical percent of carbonate in each alkali metal carbonate.
I found the molecular weight of the alkali metals plus the carbonate. Using this, I divided this mass mass of carbonate by the total. As a result, I got the following for each alkali metal carbonate:
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